14 alumni…
- Samuel Ford McGill (1815-1871)
- DMS Class of 1839, M.D.Physician, Businessman, and Liberian Politician
- Henry Jenkins Roberts (1821-1863)
- DMS Class of 1846Physician, Liberian colonist and brother of Liberia's first President, Joseph Jenkins Roberts
- Dempsey Rollo Fletcher (1825-1878)
- DMS Class of 1847, M.D.Physician and Liberian colonist
- Augustus Washington (1821-1875)
- Class of 1847Daguerreotypist, Liberian Colonist, and Politician
- Isaac Humphrey Snowden (1826-1869)
- DMS Class of 1851, M.D.Physician and Liberian colonist
- Charles Benjamin Dunbar (1829-1878)
- DMS Class of 1853, M.D.Physician, politician and Liberian colonist
- Daniel Laing, Jr. (1824-1869)
- DMS Class of 1854, M.D.Physician and Liberian colonist
- Edward Garrison Draper (1834-1858)
- Class of 1855, A.B.First Black College-Educated Lawyer for Liberia
- John Anthony Parm (1840-1913)
- DMS Class of 1871, M.D.Liberian-born physician and U.S. Vice-Consul to Sierra Leone
- John Naustedla Lewis (1845-1935)
- DMS Class of 1873, M.D.Liberian-born physician who trained at Dartmouth and returned to Liberia
- Hilary John Moore (1858-1904)
- DMS Class of 1883, M.D.Physician and Liberian colonist
- Cornelius McKane (1862-1912)
- DMS Class of 1892Physician and founder of hospitals in Georgia and Liberia with Alice Woodby McKane
- Paulus Moort (1851-1903)
- DMS Class of 1892Episcopal bishop and physician in Liberia
- Elijah Henry Allen, Jr. (1903-1960)
- Class of 1923, A.B.Physician in Louisville, Kentucky and Liberia